The Reds travel to Naples to take on Carlo Ancelotti's side with Jurgen Klopp in a bullish mood after seeing his side rescue a point late on at Chelsea to maintain their unbeaten start in the Premier League
After beating Paris Saint-Germain, safely negotiating an away trip to the intimidating San Paolo will all but secure their passage to the next round if, as expected, they beat Red Star in back-to-back games after this one
Klopp will be hungry to earn a shot at redemption after being cruelly denied in the final last season with Mohamed Salah limping off injured
The focus appears to be there already though, having rattled and outplayed PSG at Anfield
If they can cope and even thrive in one of the toughest grounds in European football tonight, they will begin to be talked about as favourites for the tournament
Live updates and reaction can be found below. The game is live on BT Sport and UK subscribers can live stream through the app on mobile devices here
NapolI: Ospina; Maksimovic, Koulibaly, Albiol, Mario Rui; Allan, Hamsik, Fabián Ruiz; Callejón, Milik, Insigne Liverpool: Alisson; Alexander-Arnold, Gomez, Van Dijk, Robertson; Wijnaldum, Milner, Keita; Salah, Mane, Firmino poll loading Will Liverpool reach the Champions League final again this year? 19000+ VOTES SO FAR YES NO Key EventsPredicted line-ups12:5120:1516 minsSTATSOverall Possession RatioPossession20:1515 minsminute by minute Napoli win a corner on the left wing and Milik rises to meet the cross from Insigne, but no blue shirt can latch on to his flick-on in the box, allowing Keita to head away before Alexander-Arnold boots the ball clear
20:1313 minsminute by minute Firmino tries to stab the ball over the top for Salah, but Rui reads the danger and heads the ball to safety
There's not much rhythm to Liverpool's play at the moment.20:1111 minsminute by minute CLOSE! Napoli come inches away from breaking the deadlock
Callejon lifts a precise ball over the top for Insigne in the left inside channel
The forward pulls the trigger on a left-footed strike across Alisson, but the ball trickles just wide of the post
20:1010 minsminute by minute Liverpool probe on the edge of the box, but Milner is unable to find Salah in space in the right inside channel
20:099 minsminute by minute Firmino tries to turn the ball around the corner for Salah's run, but the forward stops in his tracks
He may have been offside on the edge of the box had he collected the ball.20:097 minsminute by minute Insigne is caught offside, attempting to latch on to Allan's ball over the top
Liverpool immediately return the favour when Mane moves too soon when trying to break away from Keita's offload
20:066 minsminute by minute It has been a quiet start to the match from both teams as they size each other up, looking for potential weaknesses
20:044 minsminute by minute Salah has space down the right flank, but he fails to control Alexander-Arnold's ball forward, sendig it out for a Napoli throw-in
20:022 minsminute by minute Callejon has a dart down the right flank, but Robertson gets across to cover his ground to make the clearance
20:001 minsminute by minute We're underway at the Stadio San Paolo.19:48 In the last competitive meeting between these two sides in November 2010, Liverpool won 3-1 at Anfield courtesy of a Steven Gerrard hat-trick
The only previous meeting in Naples finished goalless in October 2010.19:48 Since the start of last season, only Cristiano Ronaldo (15) has scored more Champions League goals than Firmino (11)19:47 Liverpool have made one change from their draw against Chelsea at the weekend
Henderson drops to the bench as Keita comes back into the midfield. Milner takes the captain's armband from his team-mate this evening
Sturridge's heroics against Chelsea are not enough to earn him a starting berth ahead of the settled front three
19:4419:42 Napoli have made three changes from their defeat at the hands of Juventus at the weekend
Milik, Ruiz and Maksimovic come into the fold for Carlo Ancelotti's men, with Hysaj, Mertens and Zielinski dropping to the bench from their loss in Serie A
19:39 Liverpool subs: Fabinho, Dejan Lovren, Jordan Henderson, Daniel Sturridge, Alberto Moreno, Simon Mignolet, Xherdan Shaqiri
19:38 LIVERPOOL (4-3-3): Alisson; Trent Alexander-Arnold, Joe Gomez, Virgil van Dijk, Andrew Robertson; Naby Keita, James Milner, Georginio Wijnaldum; Mohamed Salah, Roberto Firmino, Sadio Mane
19:35 Napoli subs: Simone Verdi, Dries Mertens, Piotr Zielinski, Elseid Hysaj, Orestis Karnezis, Marko Rog, Amadou Diawara
19:34 NAPOLI (4-3-3): David Ospina; Nikola Maksimovic, Raul Albiol, Kalidou Koulibaly, Mario Rui; Allan, Marek Hamsik, Fabian Ruiz; Jose Callejon, Arkadiusz Milik, Lorenzo Insigne
19:33 Let's take a look at the two teams this evening, starting with the home side
19:31 Roberto Firmino's last-minute winner guided Liverpool to a victory over PSG in their opener
Goals from Daniel Sturridge and James Milner had put the Reds ahead at Anfield, only for Thomas Meunier and Kylian Mbappe to bring the French outfit back on level terms
However, the Brazilian pounced in stoppage time to secure the points, which could be very important come the end of the group stage
19:30 Napoli drew their opening match of the competition, playing out a goalless draw against Red Star Belgrade
There will be work for the Italian outfit to do to match the points' totals of Liverpool and Paris Saint-Germain over the course of the group stage, making a positive result this evening vital factor in their hopes of reaching the knockout phase
19:27Napoli fans finding their voices It will be a big atmosphere in Naples. Will Liverpool respond? We're half an hour from kick-off
19:26 Good evening and welcome to the live commentary of the Champions League Group C clash between Napoli and Liverpool at the Stadio San Paolo
18:45Team news! Here's how the two sides will line up this evening. NapolI: Ospina; Maksimovic, Koulibaly, Albiol, Mario Rui; Allan, Hamsik, Fabián Ruiz; Callejón, Milik, Insigne Liverpool: Alisson, Alexander-Arnold, Gomez, Van Dijk, Robertson, Wijnaldum, Milner, Keita, Salah, Mane, Firmino18:07What Klopp thought of the squad he inherited from Rodgers Jurgen Klopp took over from Brendan Rodgers as Liverpool boss in October 2015, and details on what he thought of the squad he inherited have emerged
Despite signing a four-year deal the season before, the Northern Irishman was sacked after Liverpool put together a string of poor performances
Two terms before and Rodgers had come agonisingly close to guiding Liverpool to a Premier League title, only falling short at the last hurdle
The German inherited a team that could potentially challenge for the league, but they were falling some way short
Read more here.12:51KEY EVENTPredicted line-ups Liverpool take on Napoli at the Stadio San Paolo buoyed by a smart start to the season and a destruction of the Italian side back in August
Jurgen Klopp's side thrashed Carlo Ancelotti's men 5-0 in Dublin, tearing the Partenopei apart at the Aviva Stadium
That match left Napoli's dangerous attacker Lorenzo Insigne stunned by how good one player was in particular
"Roberto Firmino is the most decisive player," the Italy international declared on Tuesday
"He plays between the lines and opens the spaced for teammates." The Brazilian international will lead Liverpool's attack, having scored the winner against PSG in the opening group game at Anfield
Predicted Liverpool XI: Alisson; Alexander-Arnold, Gomez, Van Dijk, Robertson; Wijnaldum, Henderson, Milner; Salah, Firmino, Mane
Predicted Napoli XI: Ospina; Hysaj, Albiol, Koulibaly, Mario Rui; Allan, Zielinski, Hamsik; Callejon, Mertens, Insigne

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